caa a22 4500 463238842 CHVBK 20180405153306.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10947-007-0017-9 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0017-9 Synthesis, structure, and properties of [RuNO(NH3)4OH][PtCl4] and [RuNO(NH3)4OH][PdCl4] [Elektronische Daten] [O. Plyusnina, V. Emel'yanov, I. Baidina, I. Korol'kov, S. Gromilov] Double complex [RuNO(NH3)4OH][PtCl4] (I) and [RuNO(NH3)4OH][PdCl4] (II) salts have been prepared and explored with TGA, IR spectroscopy, powder and single crystals X-ray diffraction. Crystal phases of I and II are isostructural (space group Cmc21) and have the following crystal chemical characteristics: a = 8.106 Å, b = 18.190(3) Å, c = 8.097 Å, V = 1194.0 Å3, Z = 4, ρcalc = 3.077 g/cm3 (I), and a = 8.116 Å, b = 18.135 Å, c = 8.062 Å, V = 1186.5 Å3, Z = 4, ρcalc = 2.600 g/cm3 (II). The product of thermal decomposition of I in inert and hydrogen atmospheres is a substitution solid solution Pt0.5Ru0.5 with the parameter of the FCC unit cell a = 3.856(3) Å. Thermolysis of II affords two-phase mixtures of limited solid solutions of the metals featuring Ru-based HCP and Pd-based FCC cells. Springer Science+Business Media, Inc., 2007 complex salt nationallicence ruthenium nationallicence platinum nationallicence palladium nationallicence X-ray diffraction analysis nationallicence crystal chemistry nationallicence substitution solid solution nationallicence Plyusnina O. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Emel'yanov V. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Korol'kov I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Gromilov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Kluwer Academic Publishers-Consultants Bureau 48/1(2007-01-01), 114-121 0022-4766 48:1<114 2007 48 10947 https://doi.org/10.1007/s10947-007-0017-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0017-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Plyusnina O. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Emel'yanov V. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Korol'kov I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Gromilov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Kluwer Academic Publishers-Consultants Bureau 48/1(2007-01-01), 114-121 0022-4766 48:1<114 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer