caa a22 4500 463238990 CHVBK 20180405153307.0 cr unu---uuuuu 170326e20070101xx s 000 0 eng 10.1007/s10947-007-0021-0 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0021-0 Investigation of the formation process of nanosized particles of Ru(III) [Elektronische Daten] [S. Troitskii, M. Fedotov, D. Kochubei, B. Novgorodov, A. Chuvilin, V. Likholobov] 17O, 35Cl, 133Cs NMR spectroscopy, static magnetic susceptibility measurements, EXAFS, UV spectroscopy, pH measurements, and electron microscopy are applied to investigate alkaline hydrolysis of aqueous K2[RuCl5H2O]. It is found that on addition of a base ligand substitution is accompanied by polycondensation processes which afford filament structures consisting of Ru(OH)4Cl2 octahedra bonded by single OH-bridges. When polynuclear compounds are sorbed on the surface of carbonic substrates, the filaments aggregate into nanosized particles which have a diameter of approximately 2.0 nm with a narrow size distribution. Springer Science+Business Media, Inc., 2007 Ru(III) nationallicence hydrolysis nationallicence nanosized particles nationallicence NMR nationallicence magnetic susceptibility nationallicence EXAFS nationallicence UV spectrometry nationallicence pH measurements nationallicence electron microscopy nationallicence Troitskii S. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Fedotov M. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Kochubei D. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Novgorodov B. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Chuvilin A. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Likholobov V. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Kluwer Academic Publishers-Consultants Bureau 48/1(2007-01-01), 144-149 0022-4766 48:1<144 2007 48 10947 https://doi.org/10.1007/s10947-007-0021-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0021-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Troitskii S. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Fedotov M. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Kochubei D. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Novgorodov B. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Chuvilin A. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Likholobov V. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Kluwer Academic Publishers-Consultants Bureau 48/1(2007-01-01), 144-149 0022-4766 48:1<144 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer