caa a22 4500 463239148 CHVBK 20180405153307.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10947-007-0179-5 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0179-5 Crystal structures of the octahedral rhenium cluster compexes Cs4[Re6S8(OH)6]·6H2O and Cs4[Re6Se8(OH)6]·8H2O [Elektronische Daten] [K. Brylev, Yu. Mironov, S.-J. Kim, V. Fedorov] The salts Cs4[Re6S8(OH)6]·6H2O (1) and Cs4[Re6Se8(OH)6]·8H2O (2) were obtained by the reactions of Re6S8Br2 and Re6Se8Br2 with a CsOH melt with further solution of the products in water and crystallization of 1 and 2 from the aqueous solutions. The structure of the compounds was established by X-ray single crystal diffraction analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 14.175(2) Å, b = 11.321(2) Å, c = 17.503(2) Å, V = 2808.5(7) Å3, Z = 4, d calc = 5.003 g/cm3; compound 2 crystallizes in the triclinic space group $$P\bar 1$$ with unit cell parameters a = 9.020(4) Å, b = 9.127(4) Å, c = 10.289(4) Å, α = 79.589(7)°, β = 75.829(7)°, γ = 72.186(7)°, V = 776.8(6) Å3, Z = 1, d calc = 5.402 g/cm3. Springer Science+Business Media, Inc., 2007 octahedral cluster nationallicence rhenium nationallicence synthesis nationallicence crystal structure nationallicence hydrate nationallicence Brylev K. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Mironov Yu A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Kim S.-J EWHA Women's University, Seoul, Korean Republic aut Fedorov V. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/6(2007-11-01), 1118-1123 0022-4766 48:6<1118 2007 48 10947 https://doi.org/10.1007/s10947-007-0179-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0179-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Brylev K. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Mironov Yu A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Kim S.-J EWHA Women's University, Seoul, Korean Republic aut NATIONALLICENCE 700 1- Fedorov V. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/6(2007-11-01), 1118-1123 0022-4766 48:6<1118 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer