caa a22 4500 463239199 CHVBK 20180405153307.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10947-007-0181-y doi (NATIONALLICENCE)springer-10.1007/s10947-007-0181-y Structure of aniline-containing Co(III) trans -dioximates with the [ZrF6]2− anion [Elektronische Daten] [A. Rija, É. Coropceanu, O. Bologa, S. Malinovskii, M. Gdaniec] Two new coordination compounds, trans-octahedral aniline-containing Co(III) dioximates [Co(DH)2(Anil)2]2[ZrF6]·2H2O (I) and [Co(NioxH)2(Anil)2]2[ZrF6]·3H2O (II), where DH− is the dimethylglyoxime monoanion, and NioxH− is the 1,2-cyclohexanedionedioxime monoanion, were synthesized, and their crystal structures were studied by XRD. In I, two centrosymmetric, crystallographically independent [Co(DH)2(Anil)2]+ complex cations (A and B) are linked by a system of hydrogen bonds, the [ZrF6]2− centrosymmetric anion, and the crystallization water molecules into a three-dimensional framework. The coordination polyhedron of the Co3+ atom in I and II is a slightly distorted N6 octahedron formed by four nitrogen atoms of the two dioxime residues and two amine nitrogen atoms of the aniline fragment. The deviation of the cobalt atom from the plane of the metallocycle in II is up to 0.012 Å. The [ZrF6]2− outer-spheric anions and crystallization water molecules dominate in the crystal structures. Springer Science+Business Media, Inc., 2007 dioximates nationallicence complex cation nationallicence π-π interaction nationallicence hydrogen bond nationallicence Rija A. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut Coropceanu É. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut Bologa O. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut Malinovskii S. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut Gdaniec M. Faculty of Chemistry, A. Mickiewicz University, Poznan, Poland aut Journal of Structural Chemistry Springer US 48/6(2007-11-01), 1132-1137 0022-4766 48:6<1132 2007 48 10947 https://doi.org/10.1007/s10947-007-0181-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0181-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Rija A. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut NATIONALLICENCE 700 1- Coropceanu É. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut NATIONALLICENCE 700 1- Bologa O. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut NATIONALLICENCE 700 1- Malinovskii S. Institute of Chemistry, Academy of Sciences, Chisinau, Moldova Republic aut NATIONALLICENCE 700 1- Gdaniec M. Faculty of Chemistry, A. Mickiewicz University, Poznan, Poland aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/6(2007-11-01), 1132-1137 0022-4766 48:6<1132 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer