caa a22 4500 463239202 CHVBK 20180405153307.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10947-007-0169-7 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0169-7 Physicochemical study of rhodium sulfite [Elektronische Daten] [A. Belyaev, V. Il'yashevich, P. Plyusnin] Diamagnetic rhodium sulfite Na15(NH4)3[Rh4(μ-SO3)6(SO3)7(H2O)5]·10H2O was synthesized. An X-ray photoelectron spectroscopy study and chemical analysis revealed that rhodium in this compound was in the oxidation state 2+. The thermal and chemical properties of the compound were investigated. Based on XRPA, IR, and EPR spectroscopy and analytical data about the chemical properties, a hypothesis about the structure of the complex has been formulated. Springer Science+Business Media, Inc., 2007 complex nationallicence rhodium nationallicence sulfite ion nationallicence synthesis nationallicence XPS nationallicence IR spectroscopy nationallicence TGA nationallicence magnetic properties nationallicence structure nationallicence Belyaev A. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Il'yashevich V. "V. N. Gulidov Nonferrous Metals Plant” OAO, Krasnoyarsk aut Plyusnin P. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/6(2007-11-01), 1046-1052 0022-4766 48:6<1046 2007 48 10947 https://doi.org/10.1007/s10947-007-0169-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0169-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Belyaev A. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Il'yashevich V. "V. N. Gulidov Nonferrous Metals Plant” OAO, Krasnoyarsk aut NATIONALLICENCE 700 1- Plyusnin P. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/6(2007-11-01), 1046-1052 0022-4766 48:6<1046 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer