caa a22 4500 463239644 CHVBK 20180405153309.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10947-007-0075-z doi (NATIONALLICENCE)springer-10.1007/s10947-007-0075-z Synthesis and structure of a complex of copper(II) bromide with bis(benzotriazol-1-yl)methane [Elektronische Daten] [E. Lider, A. Potapov, E. Peresypkina, A. Smolentsev, V. Ikorskii, A. Khlebnikov, L. Lavrenova] The preparation technique of a complex of copper(II) bromide with bis(benzotriazol-1-yl)methane (L), (Cu2L2Br4)n, is developed. The compound is studied by single crystal and powder X-ray diffraction and static magnetic susceptibility techniques. According to single crystal XRD data, the complex has a layered structure determined by bidentate bridging coordination of L with N(3) and N(3′) atoms to copper(II). The elementary unit of {Cu2(µ-Br)2Br2} polymer has a binuclear structure. The coordination polyhedron is a trigonal pyramid, and the coordination core is CuN2Br3. The temperature dependence of effective magnetic moment is studied within an interval of 2-300 K. The nature of the µeff(T) dependence indicates that antiferromagnetic exchange interactions dominate in exchange clusters of the complex with an even number of paramagnetic centers. Springer Science+Business Media, Inc., 2007 copper nationallicence bis(benzotriazol-1-yl)methane nationallicence complex nationallicence synthesis nationallicence crystal and molecular structure nationallicence magnetic properties nationallicence Lider E. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Potapov A. I. I. Polzunov Altai State Technical University, Barnaul aut Peresypkina E. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Smolentsev A. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Ikorskii V. International tomography center, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Khlebnikov A. I. I. Polzunov Altai State Technical University, Barnaul aut Lavrenova L. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/3(2007-05-01), 500-505 0022-4766 48:3<500 2007 48 10947 https://doi.org/10.1007/s10947-007-0075-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0075-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lider E. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Potapov A. I. I. Polzunov Altai State Technical University, Barnaul aut NATIONALLICENCE 700 1- Peresypkina E. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Smolentsev A. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Ikorskii V. International tomography center, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Khlebnikov A. I. I. Polzunov Altai State Technical University, Barnaul aut NATIONALLICENCE 700 1- Lavrenova L. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/3(2007-05-01), 500-505 0022-4766 48:3<500 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer