caa a22 4500 463239695 CHVBK 20180405153309.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10947-007-0060-6 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0060-6 Some peculiarities of manifestations of the isotope effect in structural transformations of molecules [Elektronische Daten] [L. Gribov, V. Baranov, V. Dement'ev] We consider the effect of the isotopic substitution on the characteristics of structural transformations of molecules. Attention is paid to the probability factor not taken into account in the kinetic isotope effect theory earlier. This factor can prove to be determining in a number of cases, and it results in not only quantitative, but also qualitative changes in the kinetics of the structural transformation process. For example, there may appear or disappear the induction of the reaction and the time dependence of the reaction constant, the inverse ratio of the yields of obtained products, and so on. Springer Science+Business Media, Inc., 2007 structural transformations nationallicence kinetic isotope effect nationallicence radiationless transition probability nationallicence Gribov L. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow aut Baranov V. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow aut Dement'ev V. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow aut Journal of Structural Chemistry Springer US 48/3(2007-05-01), 393-399 0022-4766 48:3<393 2007 48 10947 https://doi.org/10.1007/s10947-007-0060-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0060-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gribov L. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Baranov V. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Dement'ev V. V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/3(2007-05-01), 393-399 0022-4766 48:3<393 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer