caa a22 4500 463239709 CHVBK 20180405153309.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10947-007-0069-x doi (NATIONALLICENCE)springer-10.1007/s10947-007-0069-x 1H and 7Li NMR in defect cobaltite Li0.6CoO2 [Elektronische Daten] [D. Kellerman, S. Gabuda, N. Zhuravlev, A. Semenova, T. Denisova, R. Pletnev] Within a temperature range of 120-330 K, 7Li NMR spectra in Li0.6CoO2 are obtained. It is shown that as the temperature increases, both smooth and stepwise variation of 7Li NMR contact shifts occurs. The observed effects are explained by the occupation of the excited levels of cobalt ions. The stepwise change of the resonance line width depending on the temperature is revealed. It is driven by the features of the diffusive motion of lithium ions. The calculation of the 1H NMR line shape provides the determination of the ratio of one-, two-, and three-spin proton clusters in Li0.6CoO2·xH2O. Springer Science+Business Media, Inc., 2007 lithium cobaltite nationallicence NMR nationallicence electroconductivity nationallicence magnetic susceptibility nationallicence diffusion nationallicence polaron nationallicence Kellerman D. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut Gabuda S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Zhuravlev N. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut Semenova A. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut Denisova T. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut Pletnev R. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut Journal of Structural Chemistry Springer US 48/3(2007-05-01), 462-466 0022-4766 48:3<462 2007 48 10947 https://doi.org/10.1007/s10947-007-0069-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0069-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kellerman D. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut NATIONALLICENCE 700 1- Gabuda S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Zhuravlev N. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut NATIONALLICENCE 700 1- Semenova A. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut NATIONALLICENCE 700 1- Denisova T. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut NATIONALLICENCE 700 1- Pletnev R. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/3(2007-05-01), 462-466 0022-4766 48:3<462 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer