caa a22 4500 463240065 CHVBK 20180405153310.0 cr unu---uuuuu 170326e20070701xx s 000 0 eng 10.1007/s10947-007-0108-7 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0108-7 Crystal structure of lansoprazole sulfone [Elektronische Daten] [G. Swamy, K. Ravikumar] The structure of 2-({[3-methyl-4-(2,2,2-trifluoroethoxy)-2-pyridinyl]methyl} sulfonyl)-1H-1,3-benzimidazole, C16H14N3O3F3S, has been solved. The compound belongs to the monoclinic space group (P21/c) with cell parameters a = 8.8693(9) Å, b = 23.369(2) Å, c = 8.6141(8) Å, β = 104.68(1)°, V = 1727.2(3) Å3, Z = 4. The final R and wR(F 2) values were 0.070 and 0.147, respectively. The title molecule has a ‘Z' shape in the crystal structure. The fused benzimidazole moiety and the pyridine ring are nearly coplanar. The molecules are linked by N-H N and C-H O hydrogen bonds into chains of edge-fused R 2 2 (14), R 2 2 R 2 2 (8), and R 2 2 (18) rings along the c-axis. The crystal lattice is further strengthened by π-π stacking interactions. Springer Science+Business Media, Inc., 2007 Crystal structure nationallicence benzimidazole nationallicence X-ray diffraction nationallicence hydrogen bonding nationallicence Swamy G. Indian Institute of Chemical Technology, Laboratory of X-ray Crystallography, 500 007, Hyderabad, India aut Ravikumar K. Indian Institute of Chemical Technology, Laboratory of X-ray Crystallography, 500 007, Hyderabad, India aut Journal of Structural Chemistry Springer US 48/4(2007-07-01), 715-718 0022-4766 48:4<715 2007 48 10947 https://doi.org/10.1007/s10947-007-0108-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0108-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Swamy G. Indian Institute of Chemical Technology, Laboratory of X-ray Crystallography, 500 007, Hyderabad, India aut NATIONALLICENCE 700 1- Ravikumar K. Indian Institute of Chemical Technology, Laboratory of X-ray Crystallography, 500 007, Hyderabad, India aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/4(2007-07-01), 715-718 0022-4766 48:4<715 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer