caa a22 4500 463240227 CHVBK 20180405153310.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10947-007-0143-4 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0143-4 Crystal structure of [ethylenediamine- N,N ′-di(3-propionato)copper(II)]- tris [dichloromercury(II)] [Cu(Eddp)·(HgCl2)3]n [Elektronische Daten] [M. Zabel, A. Poznyak, V. Pavlovskii] Crystals of [Cu(Eddp)·(HgCl2)3]n (monoclinic, a = 9.7547(7) Å, b = 18.3716(12) Å, c = 11.7811(9) Å, β = 94.828(9)°, Z = 4, space group P21/n) are made of infinite sheets involving dimeric complexes [Cu2(Eddp)2] interacting with quasi-molecules of HgCl2 (Hg-Cl 2.29-2.36 Å). In the dimers, copper atoms are squarely surrounded by two N atoms and two O atoms of the ethylendiamine-N,N′-di(3-propionate) anion, and atom from a neighboring Eddp ion in the apical position; the second apical position is occupied by a Cl atom of one of HgCl2 molecules. Weak Hg-Cl interactions (2.98-3.07 Å) join the molecules of HgCl2 in almost planar centrosymmetrical Hg6Cl12 hexamers, and further (Hg-Cl 3.168(3) Å, 3.250(2) Å) in infinite chains of the hexamers. Finally, the dimeric copper complexes are linked to six Hg atoms of four adjacent hexamers by virtue of their oxygen atoms (Hg-O 2.322(8), 2.609(6) Å, 2.730(5) Å). Springer Science+Business Media, Inc., 2007 crystal structure nationallicence ethylenediamine- N,N ′-dipropionatocopper(II) nationallicence adduct of mercury(II) dichloride nationallicence Zabel M. Institut für Anorganische Chemie, Universitat Regensburg, Deutschland aut Poznyak A. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, Minsk aut Pavlovskii V. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, Minsk aut Journal of Structural Chemistry Springer US 48/5(2007-09-01), 968-972 0022-4766 48:5<968 2007 48 10947 https://doi.org/10.1007/s10947-007-0143-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0143-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zabel M. Institut für Anorganische Chemie, Universitat Regensburg, Deutschland aut NATIONALLICENCE 700 1- Poznyak A. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, Minsk aut NATIONALLICENCE 700 1- Pavlovskii V. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, Minsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/5(2007-09-01), 968-972 0022-4766 48:5<968 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer