caa a22 4500 463240235 CHVBK 20180405153310.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10947-007-0126-5 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0126-5 Hydrolysis of antimony(III) fluoride complexes [Elektronische Daten] [N. Laptash, E. Kovaleva, A. Mashkovskii, A. Beloliptsev, L. Zemnukhova] Vibrational and 17O NMR spectroscopy in combination with quantum chemical calculations are used to investigate the hydrolysis of antimony(III) fluoride complexes. A hydrolytic decomposition of SbF3 and [SbF4]− is accompanied by oligomerization with the formation of edge-and corner-connected dimers ([Sb2O2F4]2−, [Sb2OF8]4−) and trimers ([Sb3O3F6]3−, [Sb3OF9]2−) with bridging oxygen atoms. The hydrolysis of [SbF4]− is also characterized by the presence in the solution of a discrete cation of [SbF5]2− which is least hydrolized. Only a partial isomorphic substitution of fluoride ion by hydroxide one is possible, which is reflected in the composition of K2Sb(OH)xF5−x (x = 0.3) crystals isolated from the fluoride aqueous solution. Springer Science+Business Media, Inc., 2007 antimony trifluoride nationallicence fluoroantimonates(III) nationallicence hydrolysis nationallicence oligomerization nationallicence vibrational spectra nationallicence 17O NMR nationallicence quantum chemistry nationallicence Laptash N. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut Kovaleva E. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut Mashkovskii A. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut Beloliptsev A. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut Zemnukhova L. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut Journal of Structural Chemistry Springer US 48/5(2007-09-01), 848-854 0022-4766 48:5<848 2007 48 10947 https://doi.org/10.1007/s10947-007-0126-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0126-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Laptash N. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut NATIONALLICENCE 700 1- Kovaleva E. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut NATIONALLICENCE 700 1- Mashkovskii A. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut NATIONALLICENCE 700 1- Beloliptsev A. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut NATIONALLICENCE 700 1- Zemnukhova L. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/5(2007-09-01), 848-854 0022-4766 48:5<848 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer