caa a22 4500 463240243 CHVBK 20180405153310.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10947-007-0145-2 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0145-2 Complex of palladium(II) with a macrocylic ligand derived from thiophene-2,5-carboxamide and bipyrrole [Elektronische Daten] [E. Kataev, G. Lavrov, V. Roznyatovskii, V. Khrustalev] The interaction of a Pd(II) salt with macrocyclic ligand 1 containing thiophene-2,5-carboxamide and bipyrrole fragments is studied. It is demonstrated that only mono-palladium complex 2 is formed in the reaction of PdCl2(CH3CN)2 with ligand 1. Complex 2 was isolated as crystalline compound 2b additionally involving also triethylammonium acetate and solvent molecules. According to single crystal XRD data, the crystals of complex 2b have the composition of [C50H45N6O4PdS]−[C6H16N]+· 1/4(C5H12)·CH2Cl2, triclinic, space group $$P\bar 1$$ , a = 14.9608(5) Å, b = 17.5574(6) Å, c = 22.5893(8) Å, α = 75.218(5)°, β = 74.086(5)°, γ = 81.244(5)°, V = 5495.7(4) Å3, Z = 4 (two independent formula units), d calc = 1.375 g/cm3, μ = 0.526 mm−1. The central atom of palladium(II) is coordinated with amide, imine, pyrrole nitrogen atoms, and the oxygen atom of triethylammonium acetate. Springer Science+Business Media, Inc., 2007 expanded porphyrins nationallicence macrocyclic ligand nationallicence bipyrrole nationallicence anion binding nationallicence palladium complex nationallicence Kataev E. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut Lavrov G. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut Roznyatovskii V. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut Khrustalev V. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut Journal of Structural Chemistry Springer US 48/5(2007-09-01), 977-980 0022-4766 48:5<977 2007 48 10947 https://doi.org/10.1007/s10947-007-0145-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0145-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kataev E. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Lavrov G. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Roznyatovskii V. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut NATIONALLICENCE 700 1- Khrustalev V. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/5(2007-09-01), 977-980 0022-4766 48:5<977 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer