caa a22 4500 463240251 CHVBK 20180405153310.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10947-007-0144-3 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0144-3 Crystal structure of Na3(NH4)2[Ir(SO3)2Cl4]·4H2O [Elektronische Daten] [I. Baidina, V. Il'yashevich, V. Malakhov, A. Belyaev] The complex Na3(NH4)2[Ir(SO3)2Cl4]·4H2O was examined with single crystal X-ray diffraction and IR spectroscopy. Crystal data: a = 7.3144(4) Å, b = 10.0698(5) Å, c = 12.3748(6) Å, β = 106.203(1)°, V = 875.26(8) Å3, space group P21/c, Z = 2, d calc = 2.547 g/cm3. In the complex anion two trans SO 3 2− groups are coordinated to iridium through the S atom. The splitting of O-H bending vibrations of crystallization water molecules and N-H ones of the ammonium cation is considered in the context of different types of interactions with the closest neighbors in the structure. Springer Science+Business Media, Inc., 2007 complex salt nationallicence iridium nationallicence single crystal X-ray diffraction nationallicence crystal chemistry nationallicence sulfite ion nationallicence IR spectroscopy nationallicence Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Il'yashevich V. V. N. Gulidov Non-ferrous Metals Plant "Krastsvetmet”, Krasnoyarsk aut Malakhov V. V. N. Gulidov Non-ferrous Metals Plant "Krastsvetmet”, Krasnoyarsk aut Belyaev A. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/5(2007-09-01), 973-976 0022-4766 48:5<973 2007 48 10947 https://doi.org/10.1007/s10947-007-0144-3 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0144-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Il'yashevich V. V. N. Gulidov Non-ferrous Metals Plant "Krastsvetmet”, Krasnoyarsk aut NATIONALLICENCE 700 1- Malakhov V. V. N. Gulidov Non-ferrous Metals Plant "Krastsvetmet”, Krasnoyarsk aut NATIONALLICENCE 700 1- Belyaev A. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/5(2007-09-01), 973-976 0022-4766 48:5<973 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer