caa a22 4500 463240324 CHVBK 20180405153310.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10947-007-0133-6 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0133-6 Investigation of phase transitions of a pseudo-hexagonal phase of [Rh(NH3)5Cl]2[Re6S8(CN)6]·3H2O during thermal decomposition [Elektronische Daten] [S. Gromilov, K. Yusenko, E. Shusharina] A general motif of the crystal structure of [Rh(NH3)5Cl]2[Re6S8(CN)6]·3H2O is examined, and the cluster anions are found to form a pseudo-hexagonal sublattice. The thermal decomposition of [Rh(NH3)5Cl]2[Re6S8(CN)6]·3H2O is studied, and it is shown that in helium atmosphere thermolysis occurs through the formation of intermediate amorphous phases. The final product obtained at 1200°C is a disordered single-phase solid solution of Re0.75Rh0.25 based on the structure of rhenium. Powder X-ray diffraction data for solid solutions in the system of Rh-Re are surveyed. It is demonstrated that the data for phases prepared by the thermal decomposition of coordination compounds better match the theoretical state diagram than the experimental one. The dependence of atomic volume on the composition of solid solutions of RexRh1−x is derived. Springer Science+Business Media, Inc., 2007 crystal chemistry nationallicence rhodium nationallicence rhenium cluster nationallicence substitution solid solution nationallicence powder X-ray diffraction nationallicence thermal decomposition nationallicence Gromilov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Yusenko K. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Shusharina E. Nosovisirsk State University, Novosibirsk aut Journal of Structural Chemistry Springer US 48/5(2007-09-01), 899-905 0022-4766 48:5<899 2007 48 10947 https://doi.org/10.1007/s10947-007-0133-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0133-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gromilov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Yusenko K. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Shusharina E. Nosovisirsk State University, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/5(2007-09-01), 899-905 0022-4766 48:5<899 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer