caa a22 4500 463240375 CHVBK 20180405153311.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10947-007-0146-1 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0146-1 Crystal and molecular structures of 2,4-diacetyl-5-hydroxy-5-methyl-3-phenyl-N-benzyl-1-cyclohexenylamine [Elektronische Daten] [V. Sorokin, É. Grigor'eva, N. Poplevina, A. Kriven'ko, S. Solodovnikov] 2,4-Diacetyl-5-hydroxy-5-methyl-3-phenyl-N-benzyl-1-cyclohexenylamine is obtained by benzylamination of 2,4-diacetyl-5-hydroxy-5-methyl-3-phenylcyclohexanone. Based on spectral and X-ray structural data, the half-chair conformation of the cyclohexenyl ring and the pseudoequatorial orientation of all substituents, except for the pseudoaxial OH-group, are established. An intramolecular hydrogen bond N-H...O=C is revealed. Springer Science+Business Media, Inc., 2007 single crystal X-ray diffraction nationallicence enamines nationallicence cyclohexenes nationallicence Sorokin V. N. G. Chernyshevskii Saratov State University, Russia aut Grigor'eva É. N. G. Chernyshevskii Saratov State University, Russia aut Poplevina N. N. G. Chernyshevskii Saratov State University, Russia aut Kriven'ko A. N. G. Chernyshevskii Saratov State University, Russia aut Solodovnikov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/5(2007-09-01), 981-985 0022-4766 48:5<981 2007 48 10947 https://doi.org/10.1007/s10947-007-0146-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0146-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sorokin V. N. G. Chernyshevskii Saratov State University, Russia aut NATIONALLICENCE 700 1- Grigor'eva É. N. G. Chernyshevskii Saratov State University, Russia aut NATIONALLICENCE 700 1- Poplevina N. N. G. Chernyshevskii Saratov State University, Russia aut NATIONALLICENCE 700 1- Kriven'ko A. N. G. Chernyshevskii Saratov State University, Russia aut NATIONALLICENCE 700 1- Solodovnikov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/5(2007-09-01), 981-985 0022-4766 48:5<981 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer