caa a22 4500 463240405 CHVBK 20180405153311.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10947-007-0130-9 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0130-9 Development of the theory of strong electrolytes considering the concentration dependence of hydration numbers [Elektronische Daten] [A. Zaitsev, V. Afanas'ev] An expression for the Gibbs free energy is obtained that takes into account the contribution of interactions in the hydrate shells of ions and is compared with experimental data on the concentration dependence of hydration numbers. The activity coefficient derived from this expression is consistent with experiment up to the concentrations corresponding to the total solvation boundary (TSB). The relations describing the thermodynamics of solutions in the region of concentrations exceeding TSB are proposed. The analysis of the obtained expressions confirms their adequacy to experiments. Springer Science+Business Media, Inc., 2007 solvation nationallicence hydration number nationallicence total solvation boundary nationallicence activity coefficients of sodium chloride nationallicence exceeding the boundary of total solvation nationallicence Zaitsev A. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo aut Afanas'ev V. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo aut Journal of Structural Chemistry Springer US 48/5(2007-09-01), 874-881 0022-4766 48:5<874 2007 48 10947 https://doi.org/10.1007/s10947-007-0130-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0130-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zaitsev A. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo aut NATIONALLICENCE 700 1- Afanas'ev V. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/5(2007-09-01), 874-881 0022-4766 48:5<874 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer