caa a22 4500 46324043X CHVBK 20180405153311.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10947-007-0043-7 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0043-7 Synthesis and crystal structure of [Co(NH3)6][AuX4]X2 (X [Elektronische Daten] Cl−, Br−) [E. Makotchenko, I. Baidina, P. Plyusnin] [Co(NH3)6][AuX4]X2 binary complex salts, where X = Cl− (I) and Br− (II), have been obtained and defined by element, X-ray diffraction, and thermal analyses and by IR, Raman, and electron spectroscopy. The compounds are isostructural. Their structural units are the [Co(NH3)6]3+ complex cations, the [AuX4]− complex anions, and the X− anions. The plane square environment of the gold atom is completed to an elongated bipyramid by two halide ions lying at distances Au...Cl 3.245 Å for I and Au...Br 3.362 Å for II. The thermolysis products of I and II are pure gold and cobalt metal powders when thermolysis is performed under hydrogen and a mixture of metallic gold with cobalt halide in a reaction under an inert atmosphere. Springer Science+Business Media, Inc., 2007 binary complex salts of cobalt(III) hexaammoniate nationallicence gold(III) tetrahalides nationallicence ythesis nationallicence crystal structure nationallicence thermolysis nationallicence Makotchenko E. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Plyusnin P. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/2(2007-03-01), 275-281 0022-4766 48:2<275 2007 48 10947 https://doi.org/10.1007/s10947-007-0043-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0043-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Makotchenko E. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Plyusnin P. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/2(2007-03-01), 275-281 0022-4766 48:2<275 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer