caa a22 4500 463240553 CHVBK 20180405153311.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10947-007-0055-3 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0055-3 Synthesis, structure, and physicochemical properties of the Cr( iso -Bu2PS2)3 chelate compound [Elektronische Daten] [E. Sankova, L. Glinskaya, T. Kokina, R. Klevstova, S. Larionov] A paramagnetic (µef = 3.86 BM) complex Cr(i-Bu2PS2)3 (I) has been synthesized. Single crystals I were grown, and the crystal structure of the compound was determined from X-ray diffraction data (X8 APEX diffractometer, MoK α radiation, 4516 F hkl , R = 0.0604). Monoclinic crystals, space group P21/n, unit cell parameters a = 14.2665(5) Å, b = 11.4400(4) Å, c = 23.1299(8) Å, β = 90.245(1)°, V = 3775.0(2) Å3, Z = 4, d calc = 1.196 g/cm3. The structure is based on discrete mononuclear molecules. The coordination polyhedron of the Cr atom is a distorted S6 octahedron formed from the S atoms of three cyclic bidentate ligands — i-Bu2PS 2 − ions. Electron spectroscopy data correspond to the octahedral structure of the CrS6 chromophore. Springer Science+Business Media, Inc., 2007 chelate compound nationallicence Cr(III) nationallicence diisobutyldithiophosphinate ion nationallicence crystal and molecular structure nationallicence Sankova E. Novosibirsk State University, Russia aut Glinskaya L. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Kokina T. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Klevstova R. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Larionov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/2(2007-03-01), 366-371 0022-4766 48:2<366 2007 48 10947 https://doi.org/10.1007/s10947-007-0055-3 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0055-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sankova E. Novosibirsk State University, Russia aut NATIONALLICENCE 700 1- Glinskaya L. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Kokina T. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Klevstova R. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Larionov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/2(2007-03-01), 366-371 0022-4766 48:2<366 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer