caa a22 4500 463240626 CHVBK 20180405153311.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10947-007-0042-8 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0042-8 Synthesis and crystal and molecular structure of CdPhen( iso -C4H9OCS2)2 and CdPhen( n -C4H9OCS2)2 mixed-ligand complexes [Elektronische Daten] [R. Klevtsova, T. Leonova, L. Glinskaya, S. Larionov] Mixed-ligand complexes CdPhen(i-BuOCS2)2 (I) and CdPhen(n-BuOCS2)2 (II) have been synthesized. Their structures were solved using X-ray diffraction data (X8 APEX diffractometer, MoK α radiation, 1641 and 2497 F hkl , R = 0.0359 and 0.0389). Crystals I are orthorhombic with unit cell parameters a = 6.5883(3) Å, b = 19.7123(10) Å, c = 20.1936(11) Å, V = 2622.6(2) Å3; Z = 4, space group Pbcn; crystals II are monoclinic, a = 6.5845(2) Å, b = 19.1522(6) Å, c = 20.7091(7) Å, β = 97.106(1), V = 2591.5(1) Å3, Z = 4, space group C2/c. The structures consist of discrete mononuclear molecules in which the coordination polyhedron of the Cd atom is a distorted N2S4 octahedron. Molecular packing and interactions in the structures are discussed. Springer Science+Business Media, Inc., 2007 synthesis nationallicence mixed-ligand complex nationallicence Cd(II) nationallicence alkylxanthate ion nationallicence 1,10-phenanthroline nationallicence structure nationallicence Klevtsova R. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Leonova T. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Glinskaya L. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Larionov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/2(2007-03-01), 267-274 0022-4766 48:2<267 2007 48 10947 https://doi.org/10.1007/s10947-007-0042-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0042-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Klevtsova R. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Leonova T. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Glinskaya L. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Larionov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/2(2007-03-01), 267-274 0022-4766 48:2<267 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 462073610 BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer