caa a22 4500 463240642 CHVBK 20180405153311.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10947-007-0056-2 doi (NATIONALLICENCE)springer-10.1007/s10947-007-0056-2 Structure of the hexanuclear Cu(II) β-diketonate complex [Elektronische Daten] [I. Baidina, S. Gromilov, P. Stabnikov] The structure of the hexanuclear copper(II) β-diketonate complex with gfa (hexafluoroacetylacetone) and dpm (dipivalylmethanate) ligands was studied by low-temperature (T = 100 K) X-ray diffraction. Crystal data for Cu6(gfa)4(dpm)4(OH)4 [C64H84Cu6F24O20]: a = 28.2364(7) Å, b = 12.8072(3) Å, c = 24.7199(7) Å, β= 115.900(1)°, V = 8041.5(4) Å3, space group C2/m, Z = 4, d calc 1.661 g/cm3. The coordination polyhedra of the copper atoms — squares and octahedra — are formed by the oxygen atoms of the gfa and dpm ligands and groups. In all cases, the Cu-O distances vary from 1.89 Å to 2.13 Å. The complexes follow the sites of the rhombohedral sublattice with the parameters a c ≈ 14.4 Å and a c ≈ 61.5°. Springer Science+Business Media, Inc., 2007 copper nationallicence β-diketonates nationallicence X-ray diffraction analysis nationallicence crystal chemistry nationallicence Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Gromilov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Stabnikov P. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut Journal of Structural Chemistry Springer US 48/2(2007-03-01), 372-378 0022-4766 48:2<372 2007 48 10947 https://doi.org/10.1007/s10947-007-0056-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10947-007-0056-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Baidina I. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Gromilov S. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 700 1- Stabnikov P. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk aut NATIONALLICENCE 773 0- Journal of Structural Chemistry Springer US 48/2(2007-03-01), 372-378 0022-4766 48:2<372 2007 48 10947 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer