caa a22 4500 463251970 CHVBK 20180405153342.0 cr unu---uuuuu 170326e20071201xx s 000 0 eng 10.1007/s10562-007-9235-1 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9235-1 Synthesis and Characterization of Zirconia Supported Vanadium Incorporated Ammonium Salt of 12-molybdophosphoric Acid Catalyst for Aerobic Oxidation of Benzyl alcohol [Elektronische Daten] [K. Mohan Reddy, M. Balaraju, P. Sai Prasad, I. Suryanarayana, N. Lingaiah] A series of zirconia supported ammonium salt of molybdophosphoric acid (AMPV) catalysts with and with out vanadium incorporation are prepared in a single step adopting wet impregnation method. These catalysts are characterized by BET surface area, XRD, FT-IR and potentiometric titration. XRD and FT-IR techniques suggest the formation of Keggin ion on zirconia support. The high resolution FT-IR analysis reveals the incorporation of vanadium into the primary structure of Keggin ion. The catalytic functionalities of these catalysts are tested for the aerobic oxidation of benzyl alcohol. The vanadium containing AMPV results in higher selectivity towards the oxidation product compared to the catalyst without vanadium incorporation. Springer Science+Business Media, LLC, 2007 Molybdophosphoric acid nationallicence Vanadium nationallicence Zirconia nationallicence Oxidation nationallicence Benzyl alcohol nationallicence Mohan Reddy K. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut Balaraju M. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut Sai Prasad P. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut Suryanarayana I. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut Lingaiah N. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut Catalysis Letters Springer US; http://www.springer-ny.com 119/3-4(2007-12-01), 304-310 1011-372X 119:3-4<304 2007 119 10562 https://doi.org/10.1007/s10562-007-9235-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9235-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mohan Reddy K. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut NATIONALLICENCE 700 1- Balaraju M. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut NATIONALLICENCE 700 1- Sai Prasad P. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut NATIONALLICENCE 700 1- Suryanarayana I. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut NATIONALLICENCE 700 1- Lingaiah N. Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, 500 007, Hyderabad, India aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 119/3-4(2007-12-01), 304-310 1011-372X 119:3-4<304 2007 119 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer