caa a22 4500 463252233 CHVBK 20180405153343.0 cr unu---uuuuu 170326e20071101xx s 000 0 eng 10.1007/s10562-007-9199-1 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9199-1 Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-bonded Oxygen Vacancies of TiO2(110) [Elektronische Daten] [Yu Kim, Bruce Kay, J. White, Zdenek Dohnálek] The activation energies for alkene formation via dehydration of alcohols on bridge-bonded oxygen (BBO) vacancy sites of TiO2(110) is found to correlate with the inductive electron donating effect of alcohol alkyl groups as measured by the Taft parameter. Based on this correlation we conclude that the reaction involves a single transition state that undergoes concerted rupture of the C-O bond of the alkoxide and a C-H bond of the alkyl group attached to the β-carbon. Springer Science+Business Media, LLC, 2007 Alcohols nationallicence Heterogeneous catalysis nationallicence TiO2(110) nationallicence Dehydration nationallicence Oxygen vacancies nationallicence Kim Yu Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, 78712, Austin, TX, USA aut Kay Bruce Pacific Northwest National Laboratory, Fundamental Sciences Directorate and Institute for Interfacial Catalysis, 99352, Richland, WA, USA aut White J. Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, 78712, Austin, TX, USA aut Dohnálek Zdenek Pacific Northwest National Laboratory, Fundamental Sciences Directorate and Institute for Interfacial Catalysis, 99352, Richland, WA, USA aut Catalysis Letters Springer US; http://www.springer-ny.com 119/1-2(2007-11-01), 1-4 1011-372X 119:1-2<1 2007 119 10562 https://doi.org/10.1007/s10562-007-9199-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9199-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kim Yu Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, 78712, Austin, TX, USA aut NATIONALLICENCE 700 1- Kay Bruce Pacific Northwest National Laboratory, Fundamental Sciences Directorate and Institute for Interfacial Catalysis, 99352, Richland, WA, USA aut NATIONALLICENCE 700 1- White J. Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, 78712, Austin, TX, USA aut NATIONALLICENCE 700 1- Dohnálek Zdenek Pacific Northwest National Laboratory, Fundamental Sciences Directorate and Institute for Interfacial Catalysis, 99352, Richland, WA, USA aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 119/1-2(2007-11-01), 1-4 1011-372X 119:1-2<1 2007 119 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer