caa a22 4500 463252519 CHVBK 20180405153344.0 cr unu---uuuuu 170326e20070201xx s 000 0 eng 10.1007/s10562-007-9016-x doi (NATIONALLICENCE)springer-10.1007/s10562-007-9016-x Effect of noble metals in the decomposition of nitrous oxide over Fe-ferrierites [Elektronische Daten] [Zdeněk Sobalík, Kamil Jíša, Dalibor Kaucký, Alena Vondrová, Zdeňka Tvarůžková, Jana Nováková] The decomposition of nitrous oxide was studied over Fe-ferrierite, Me-ferrierites and Fe/Me-ferrierites (Me: Pt, Rh and Ru). Flow as well as batch experiments were carried out and showed a synergy between Fe and Me ions. Ions of noble metals in Fe-ferrierite increased the catalytic activity in the sequence Pt<Rh≅Ru. Addition of NO substantially decreased the decomposition of N2O over Rh/ferrierite and Ru/ferrierite, but not over bimetallic ferrierites. NO x species created during the decomposition of nitrous oxide alone as well as with addition of NO, and employment of nitrous oxide labeled with 18O allowed us to assume a changing decomposition mechanism in the presence of Me ions in Fe-ferrierites. Springer Science+Business Media, LLC, 2007 Fe-, Pt-, Rh- and Ru-ferrierites nationallicence synergy effects in Fe/Me-ferrierites nationallicence N2O decomposition nationallicence Sobalík Zdeněk J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut Jíša Kamil J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut Kaucký Dalibor J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut Vondrová Alena J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut Tvarůžková Zdeňka J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut Nováková Jana J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 113/3-4(2007-02-01), 124-129 1011-372X 113:3-4<124 2007 113 10562 https://doi.org/10.1007/s10562-007-9016-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9016-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sobalík Zdeněk J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut NATIONALLICENCE 700 1- Jíša Kamil J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut NATIONALLICENCE 700 1- Kaucký Dalibor J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut NATIONALLICENCE 700 1- Vondrová Alena J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut NATIONALLICENCE 700 1- Tvarůžková Zdeňka J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut NATIONALLICENCE 700 1- Nováková Jana J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague 8, Czech Republic aut NATIONALLICENCE 773 0- Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 113/3-4(2007-02-01), 124-129 1011-372X 113:3-4<124 2007 113 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer