caa a22 4500 463252713 CHVBK 20180405153345.0 cr unu---uuuuu 170326e20070401xx s 000 0 eng 10.1007/s10562-007-9064-2 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9064-2 Pd-based bimetallic catalysts prepared by replacement reactions [Elektronische Daten] [Songrui Wang, Wei Lin, Yuexiang Zhu, Youchang Xie, John McCormick, Wei Huang, Jingguang Chen] Several Pd-based bimetallic catalysts, Pd/Co, Pd/Ni and Pd/Cu, were synthesized by replacement reactions. The catalysts were characterized by XRD and CO chemisorption and their catalytic properties were evaluated using cyclohexene self-hydrogenation. The results suggest that the high catalytic activity of Pd/Ni is most likely due to the monolayer-dispersion of Pd on the Ni surface. The results also suggest that Pd is monolayer-dispersed on the Co surface in Pd/Co, whereas Pd forms surface alloy or solid solution with Cu in Pd/Cu. Springer Science+Business Media, LLC, 2007 Pd/Co nationallicence Pd/Ni nationallicence Pd/Cu nationallicence bimetallic catalysts nationallicence cyclohexene self-hydrogenation nationallicence monolayer-dispersed catalysts nationallicence CO chemisorption nationallicence Wang Songrui Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut Lin Wei Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut Zhu Yuexiang Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut Xie Youchang Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut McCormick John Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), University of Delaware, 19716, Newark, DE, USA aut Huang Wei Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), University of Delaware, 19716, Newark, DE, USA aut Chen Jingguang Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), University of Delaware, 19716, Newark, DE, USA aut Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/3-4(2007-04-01), 169-173 1011-372X 114:3-4<169 2007 114 10562 https://doi.org/10.1007/s10562-007-9064-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9064-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Songrui Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut NATIONALLICENCE 700 1- Lin Wei Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut NATIONALLICENCE 700 1- Zhu Yuexiang Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut NATIONALLICENCE 700 1- Xie Youchang Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, 100871, Beijing, China aut NATIONALLICENCE 700 1- McCormick John Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), University of Delaware, 19716, Newark, DE, USA aut NATIONALLICENCE 700 1- Huang Wei Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), University of Delaware, 19716, Newark, DE, USA aut NATIONALLICENCE 700 1- Chen Jingguang Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), University of Delaware, 19716, Newark, DE, USA aut NATIONALLICENCE 773 0- Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/3-4(2007-04-01), 169-173 1011-372X 114:3-4<169 2007 114 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer