caa a22 4500 463252756 CHVBK 20180405153345.0 cr unu---uuuuu 170326e20070401xx s 000 0 eng 10.1007/s10562-007-9059-z doi (NATIONALLICENCE)springer-10.1007/s10562-007-9059-z A new and easy method for anchoring manganese salen on MCM-41 [Elektronische Daten] [P. Oliveira, A. Machado, A. Ramos, I. Fonseca, F. Braz Fernandes, A. Botelho do Rego, J. Vital] This work reports a new method to covalently attach manganese salophen complex onto MCM-41, using a diisocyanate as a binder. The prepared catalyst was tested on the liquid phase limonene oxidation reaction. Diluted t-Butyl hydroperoxide was used as oxygen supplier. Limonene oxide, carveol and carvone are formed, but the main product obtained was a polymer. The preservation of the MCM-41 channel system was checked by X-ray diffraction and nitrogen adsorption analysis. The use of the same catalyst sample in four consecutive experiments, without loss of activity, is a confirmation of the success of the anchoring process. Springer Science+Business Media, LLC, 2007 manganese Schiff base nationallicence MCM-41 nationallicence epoxidation nationallicence limonene nationallicence diisocyanate nationallicence Oliveira P. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut Machado A. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut Ramos A. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut Fonseca I. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut Braz Fernandes F. DCM, CENIMAT, FCT-UNL, 2829-516, Caparica, Portugal aut Botelho do Rego A. CQFM-CI, IST, Av. Rovisco Pais, 1049-001, Lisboa, Portugal aut Vital J. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/3-4(2007-04-01), 192-197 1011-372X 114:3-4<192 2007 114 10562 https://doi.org/10.1007/s10562-007-9059-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9059-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Oliveira P. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut NATIONALLICENCE 700 1- Machado A. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut NATIONALLICENCE 700 1- Ramos A. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut NATIONALLICENCE 700 1- Fonseca I. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut NATIONALLICENCE 700 1- Braz Fernandes F. DCM, CENIMAT, FCT-UNL, 2829-516, Caparica, Portugal aut NATIONALLICENCE 700 1- Botelho do Rego A. CQFM-CI, IST, Av. Rovisco Pais, 1049-001, Lisboa, Portugal aut NATIONALLICENCE 700 1- Vital J. REQUIMTE, CQFB, DQ, FCT-UNL, 2829-516, Caparica, Portugal aut NATIONALLICENCE 773 0- Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/3-4(2007-04-01), 192-197 1011-372X 114:3-4<192 2007 114 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer