caa a22 4500 463252802 CHVBK 20180405153345.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10562-007-9036-6 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9036-6 Structural insight on organosilica electrodes for waste-free alcohol oxidations [Elektronische Daten] [Giovanni Palmisano, Daniel Mandler, Rosaria Ciriminna, Mario Pagliaro] Organic modification of sol-gel catalytic glassy electrodes made of a thin layer of organosilica doped with nitroxyl radical TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) crucially enhances stability in the waste-free oxidation of alcohols to carbonyls in water. Structural comparison between analogous films made of organosilica and unmodified SiO2 shows that the origin of the pronounced stable activity of the ORMOSIL film lies in high hydrophobic and also in the pronounced low degree of hydrophilicity. Springer Science+Business Media, LLC, 2007 sol-gel nationallicence anodic nationallicence oxidation nationallicence TEMPO nationallicence alcohols nationallicence green chemistry nationallicence Palmisano Giovanni Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy aut Mandler Daniel Department of Inorganic and Analytical Chemistry, Hebrew University, Givat Ram, 91904, Jerusalem, Israel aut Ciriminna Rosaria Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy aut Pagliaro Mario Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy aut Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/1-2(2007-03-01), 55-58 1011-372X 114:1-2<55 2007 114 10562 https://doi.org/10.1007/s10562-007-9036-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9036-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Palmisano Giovanni Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy aut NATIONALLICENCE 700 1- Mandler Daniel Department of Inorganic and Analytical Chemistry, Hebrew University, Givat Ram, 91904, Jerusalem, Israel aut NATIONALLICENCE 700 1- Ciriminna Rosaria Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy aut NATIONALLICENCE 700 1- Pagliaro Mario Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy aut NATIONALLICENCE 773 0- Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/1-2(2007-03-01), 55-58 1011-372X 114:1-2<55 2007 114 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer