caa a22 4500 463252934 CHVBK 20180405153345.0 cr unu---uuuuu 170326e20070301xx s 000 0 eng 10.1007/s10562-007-9049-1 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9049-1 Imaging of low temperature induced SMSI on Pd/TiO2 catalysts [Elektronische Daten] [Jacinto Sá, Johannes Bernardi, James Anderson] Pd/TiO2 catalysts were found to enter an strong metal support interaction (SMSI) state after reduction at temperatures as low as 473K. This was identified as a significant loss in the CO uptake as monitored by low temperature FTIR. Electron microscopy provides direct evidence of the presence of ordered, reduced titanium oxide layers over palladium (SMSI state) for Pd/TiO2 catalysts following reduction at temperature 623K. The crystal phase was identified as Ti4O7 and this phase, once formed, was found to be stable even after exposure to atmospheric conditions. Springer Science+Business Media, LLC, 2007 low temperature induced SMSI nationallicence electron microscopy nationallicence low temperature FTIR nationallicence Ti4O7 nationallicence Sá Jacinto Surface Chemistry and Catalysis Group, Department of Chemistry, University of Aberdeen, Old Aberdeen, AB24 3UE, Meston Walk, UK aut Bernardi Johannes University Service Centre for Transmission Electron Microscopy, Vienna University of Technology, 8-10/052, A-1040, Vienna, Austria aut Anderson James Surface Chemistry and Catalysis Group, Department of Chemistry, University of Aberdeen, Old Aberdeen, AB24 3UE, Meston Walk, UK aut Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/1-2(2007-03-01), 91-95 1011-372X 114:1-2<91 2007 114 10562 https://doi.org/10.1007/s10562-007-9049-1 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9049-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sá Jacinto Surface Chemistry and Catalysis Group, Department of Chemistry, University of Aberdeen, Old Aberdeen, AB24 3UE, Meston Walk, UK aut NATIONALLICENCE 700 1- Bernardi Johannes University Service Centre for Transmission Electron Microscopy, Vienna University of Technology, 8-10/052, A-1040, Vienna, Austria aut NATIONALLICENCE 700 1- Anderson James Surface Chemistry and Catalysis Group, Department of Chemistry, University of Aberdeen, Old Aberdeen, AB24 3UE, Meston Walk, UK aut NATIONALLICENCE 773 0- Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 114/1-2(2007-03-01), 91-95 1011-372X 114:1-2<91 2007 114 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer