caa a22 4500 46325306X CHVBK 20180405153346.0 cr unu---uuuuu 170326e20070601xx s 000 0 eng 10.1007/s10562-007-9084-y doi (NATIONALLICENCE)springer-10.1007/s10562-007-9084-y Biomimic recognition and catalysis by an imprinted catalysts: a rational design of molecular self-assembly toward predetermined high specificity [Elektronische Daten] [Daonian Zhang, Songjun Li, Wuke Li, Yifeng Chen] This article presents an original work contributing to the rational design of imprinted catalyst by molecular self-assembly toward predetermined high specificity. Assembling with p-nitrophenyl phosphate as the transition state analogue (TSA) of p-nitrophenyl acetate esterolysis and 1-vinylimidazole as the functional monomer, the imprinted catalyst was prepared. An increase in the amount of assembled monomer results in a higher activity of hydrolysis, which, however, does not lead to an improvement of specificity. The best specificity is shown at the optimal self-assembly (corresponding to a stoichiometric interaction of monomer-TSA). Higher or lower an amount of assembled monomer would lead to a dramatic decrease in this specificity. Related information indicates that these may be a result of increasing specific interaction between the TSA and binding sites, which make the catalyst capable of selectively recognizing the transition state and promoting the conversion from reactant to the transition state. Springer Science+Business Media, LLC, 2007 molecular recognition nationallicence imprinted catalyst nationallicence self-assembly nationallicence Zhang Daonian Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut Li Songjun Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut Li Wuke Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut Chen Yifeng Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 115/3-4(2007-06-01), 169-175 1011-372X 115:3-4<169 2007 115 10562 https://doi.org/10.1007/s10562-007-9084-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9084-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhang Daonian Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut NATIONALLICENCE 700 1- Li Songjun Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut NATIONALLICENCE 700 1- Li Wuke Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut NATIONALLICENCE 700 1- Chen Yifeng Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 430079, Wuhan, P.R. China aut NATIONALLICENCE 773 0- Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 115/3-4(2007-06-01), 169-175 1011-372X 115:3-4<169 2007 115 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer