caa a22 4500 463253175 CHVBK 20180405153346.0 cr unu---uuuuu 170326e20070501xx s 000 0 eng 10.1007/s10562-007-9067-z doi (NATIONALLICENCE)springer-10.1007/s10562-007-9067-z New photocatalysts based on mixed-metal pyridine dicarboxylates [Elektronische Daten] [Partha Mahata, Giridhar Madras, Srinivasan Natarajan] New photocatalytically active isostructural two-dimensional mixed metal-pyridine dicarboxylates, [M(H2O)3Co{C5N1H3(COO)2}3])∞], M=Gd (1), Dy (2) and Y (3) have been prepared under hydrothermal conditions. The structure consists of a network of MO6(H2O)3, CoO3N3 polyhedral units connected by the pyridine dicarboxylates forming two-dimensional layers, which are arranged in an AAAA... fashion. The photocatalytic studies on 1 - 3 indicate that they are active catalysts for the degradation of simple organic dyes, such as Remazol brilliant blue R (RBBR) and Orange G (OG) in the presence of UV light. The compounds have also been characterized by powder XRD, IR, TGA, UV-Vis and magnetic studies. Springer Science+Business Media, LLC, 2007 photocatalysts nationallicence hydrothermal conditions nationallicence mixed-metal carboxylates nationallicence UV light nationallicence organic dyes nationallicence Mahata Partha Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012, Bangalore, India aut Madras Giridhar Department of Chemical Engineering, Indian Institute of Science, 560 012, Bangalore, India aut Natarajan Srinivasan Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012, Bangalore, India aut Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 115/1-2(2007-05-01), 27-32 1011-372X 115:1-2<27 2007 115 10562 https://doi.org/10.1007/s10562-007-9067-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9067-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mahata Partha Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012, Bangalore, India aut NATIONALLICENCE 700 1- Madras Giridhar Department of Chemical Engineering, Indian Institute of Science, 560 012, Bangalore, India aut NATIONALLICENCE 700 1- Natarajan Srinivasan Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012, Bangalore, India aut NATIONALLICENCE 773 0- Catalysis Letters Kluwer Academic Publishers-Plenum Publishers; http://www.springer-ny.com 115/1-2(2007-05-01), 27-32 1011-372X 115:1-2<27 2007 115 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer