caa a22 4500 463253213 CHVBK 20180405153346.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10562-007-9182-x doi (NATIONALLICENCE)springer-10.1007/s10562-007-9182-x A Cu/Zn/Al/Zr Fibrous Catalyst that is an Improved CO2 Hydrogenation to Methanol Catalyst [Elektronische Daten] [Xin An, Jinlu Li, Yizan Zuo, Qiang Zhang, Dezheng Wang, Jinfu Wang] A series of Cu/Zn/Al/Zr CO2 hydrogenation to methanol catalysts containing different ratios of Al/Zr were prepared using a co-precipitation procedure. SEM, TEM, and XRD characterization showed that all the catalysts comprised crystallites in a fibrous structure and their Cu/Zn crystallite dispersions were better than that of a commercial (COM) catalyst. It is suggested that the high dispersion and stability of the Cu/Zn crystallites due to the fibrous structure enhanced CO2 hydrogenation, and the added Zr component further improved the catalyst. A 5% Zr addition gave a methanol space time yield 80% higher than that on the COM catalyst. Springer Science+Business Media, LLC, 2007 Cu/Zn/Al/Zr nationallicence CO2 hydrogenation nationallicence An Xin Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut Li Jinlu Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut Zuo Yizan Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut Zhang Qiang Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut Wang Dezheng Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut Wang Jinfu Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut Catalysis Letters Springer US; http://www.springer-ny.com 118/3-4(2007-10-01), 264-269 1011-372X 118:3-4<264 2007 118 10562 https://doi.org/10.1007/s10562-007-9182-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9182-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- An Xin Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut NATIONALLICENCE 700 1- Li Jinlu Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut NATIONALLICENCE 700 1- Zuo Yizan Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut NATIONALLICENCE 700 1- Zhang Qiang Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut NATIONALLICENCE 700 1- Wang Dezheng Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut NATIONALLICENCE 700 1- Wang Jinfu Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, 100084, Beijing, China aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 118/3-4(2007-10-01), 264-269 1011-372X 118:3-4<264 2007 118 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer