caa a22 4500 463253345 CHVBK 20180405153347.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10562-007-9167-9 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9167-9 NO2 Reduction with Nitromethane over Ag/Y: A Catalyst with High Activity over a Wide Temperature Range [Elektronische Daten] [Young Yeom, Meijun Li, Wolfgang Sachtler, Eric Weitz] Nitromethane (NM) is a very efficient reductant for converting NO2 to N2 over Ag/Y: Between 140°C and 400°C, the N2 yield is close to 100%. This high N2 yield results from the ability of Ag/Y to effectively catalyze the reaction between NM and NO2. This high catalytic activity of Ag/Y is minimally affected by surface bound CN−, NC−, or acetate, all of which are stable at temperatures below ∼300°C. At T≥400°C, there is a reaction path that yields N2 from NM even in the absence of NO2. However even at 400°C, under typical deNO x conditions, most N2 molecules are formed as a result of the reaction of NM and NO2. Springer Science+Business Media, LLC, 2007 NO x reduction nationallicence deNO x nationallicence Nitromethane nationallicence Ag/Y nationallicence Zeolite nationallicence Catalysis nationallicence Yeom Young Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut Li Meijun Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut Sachtler Wolfgang Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut Weitz Eric Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut Catalysis Letters Springer US; http://www.springer-ny.com 118/3-4(2007-10-01), 173-179 1011-372X 118:3-4<173 2007 118 10562 https://doi.org/10.1007/s10562-007-9167-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9167-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yeom Young Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut NATIONALLICENCE 700 1- Li Meijun Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut NATIONALLICENCE 700 1- Sachtler Wolfgang Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut NATIONALLICENCE 700 1- Weitz Eric Department of Chemistry, Institute for Catalysis in Energy Processes, Northwestern University, 60208, Evanston, IL, USA aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 118/3-4(2007-10-01), 173-179 1011-372X 118:3-4<173 2007 118 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer