caa a22 4500 463253450 CHVBK 20180405153347.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10562-007-9205-7 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9205-7 CO Adsorbed Infrared Spectroscopy Study of Ni/Al2O3 Catalyst for CO2 Reforming of Methane [Elektronische Daten] [Xinli Zhu, Yue-ping Zhang, Chang-jun Liu] CO adsorbed infrared spectroscopy study was conducted in this work in order to better understand the significantly improved anti-coke performance of Ni/Al2O3 catalyst obtained via argon glow discharge plasma treatment. The present study revealed a significant decrease of linear to bridge (L/B) adsorbed CO for glow discharge plasma treated Ni/Al2O3, compared to that for untreated Ni/Al2O3, indicating an enhancement of close packed plane concentration. This structure change leads to lower methane turnover frequency (TOF) and better balance of carbon formation-gasification, resulting in better anti-coke property of Ni/Al2O3 for CO2 reforming of methane. Springer Science+Business Media, LLC, 2007 Methane nationallicence CO2 reforming nationallicence Ni/Al2O3 nationallicence CO adsorbed infrared spectroscopy nationallicence Plasma nationallicence Coke nationallicence Zhu Xinli Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering, Tianjin University, 300072, Tianjin, China aut Zhang Yue-ping Department of Chemistry, Tianjin University, 30072, Tianjin, China aut Liu Chang-jun Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering, Tianjin University, 300072, Tianjin, China aut Catalysis Letters Springer US; http://www.springer-ny.com 118/3-4(2007-10-01), 306-312 1011-372X 118:3-4<306 2007 118 10562 https://doi.org/10.1007/s10562-007-9205-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9205-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhu Xinli Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering, Tianjin University, 300072, Tianjin, China aut NATIONALLICENCE 700 1- Zhang Yue-ping Department of Chemistry, Tianjin University, 30072, Tianjin, China aut NATIONALLICENCE 700 1- Liu Chang-jun Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering, Tianjin University, 300072, Tianjin, China aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 118/3-4(2007-10-01), 306-312 1011-372X 118:3-4<306 2007 118 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer