caa a22 4500 463253469 CHVBK 20180405153347.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10562-007-9171-0 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9171-0 Reaction Kinetics of Methanol Carbonylation to Methyl Formate Catalyzed by CH3O− Exchange Resin [Elektronische Daten] [Yasuyoshi Iwase, Takaaki Kobayashi, Koji Inazu, Akimitsu Miyaji, Toshihide Baba] The carbonylation of methanol with CO using CH3O− exchange resin as a heterogeneous catalyst at temperatures near 350K is examined systematically in an attempt to derive kinetic rate expressions for the reaction. The activation energies for the carbonylation and decarbonylation reactions are found to be 68kJ/mol and 105kJ/mol, respectively. The CH3O− exchange resin is also shown to suffer no degradation of catalytic activity upon repeated separation and re-use at 353K. Springer Science+Business Media, LLC, 2007 Methanol carbonylation nationallicence Methyl formate nationallicence Methanol synthesis nationallicence CH3O− Exchange resin nationallicence Heterogeneous catalyst nationallicence Iwase Yasuyoshi Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut Kobayashi Takaaki Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut Inazu Koji Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut Miyaji Akimitsu Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut Baba Toshihide Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut Catalysis Letters Springer US; http://www.springer-ny.com 118/1-2(2007-10-01), 146-150 1011-372X 118:1-2<146 2007 118 10562 https://doi.org/10.1007/s10562-007-9171-0 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9171-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Iwase Yasuyoshi Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut NATIONALLICENCE 700 1- Kobayashi Takaaki Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut NATIONALLICENCE 700 1- Inazu Koji Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut NATIONALLICENCE 700 1- Miyaji Akimitsu Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut NATIONALLICENCE 700 1- Baba Toshihide Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, G1-14 4259 Nagatsuta, Midori-ku, 226-8502, Yokohama, Japan aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 118/1-2(2007-10-01), 146-150 1011-372X 118:1-2<146 2007 118 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer