caa a22 4500 463253620 CHVBK 20180405153348.0 cr unu---uuuuu 170326e20071001xx s 000 0 eng 10.1007/s10562-007-9156-z doi (NATIONALLICENCE)springer-10.1007/s10562-007-9156-z Catalytic Oxidation of Polyethylene Glycol Dodecyl Ether to Corresponding Carboxylic Acid by Gold, Palladium (Mono and Bimetallic) Nanoparticles Supported on Carbon [Elektronische Daten] [Yang Zhou, Shixing Wang, Bingjun Ding, Zhimao Yang] Mono and bimetallic catalysts based on Au and Pd nanoparticles were synthesized by sol immobilization method. The catalytic oxidation of polyethylene glycol dodecyl ether was performed using as-synthesized supported catalyst. The use of water as solvent and dioxygen as oxidant makes the reaction interesting from both an economic and environmental point of view. For 100min, the conversion of polyethylene glycol dodecyl ether using Au-Pd/C bimetallic catalyst was 38%, showing an increase of 9% for Au/C and 15% for Pd/C respectively indicating that a synergetic effect exists between Au and Pd. For the Au-Pd/C catalyst, adding Au after the prior addition and reduction of Pd metal can form the most active catalyst. Springer Science+Business Media, LLC, 2007 Gold nationallicence Palladium nationallicence Nanoparticles nationallicence Bimetallic catalysts nationallicence Oxidation nationallicence Zhou Yang Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut Wang Shixing Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut Ding Bingjun Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut Yang Zhimao Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut Catalysis Letters Springer US; http://www.springer-ny.com 118/1-2(2007-10-01), 86-90 1011-372X 118:1-2<86 2007 118 10562 https://doi.org/10.1007/s10562-007-9156-z text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9156-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhou Yang Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut NATIONALLICENCE 700 1- Wang Shixing Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut NATIONALLICENCE 700 1- Ding Bingjun Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut NATIONALLICENCE 700 1- Yang Zhimao Department of Materials Physics, School of Science, Xi'an Jiaotong University, 710049, Xian, China aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 118/1-2(2007-10-01), 86-90 1011-372X 118:1-2<86 2007 118 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer