caa a22 4500 463253809 CHVBK 20180405153348.0 cr unu---uuuuu 170326e20070901xx s 000 0 eng 10.1007/s10562-007-9123-8 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9123-8 Hydrogenation of 1,2-indanedione over heterogeneous cinchonidine-modified platinum catalysts [Elektronische Daten] [Igor Busygin, Michael Rosenholm, Esa Toukoniitty, Dmitry Murzin, Reko Leino] Hydrogenation of the prochiral diketone, 1,2-indanedione was for the first time investigated using cinchonidine-modified Pt/Al2O3 as a catalyst. The influence of the reaction parameters on catalyst activity, regio- and enantioselectivity was studied revealing fully regioselective hydrogenation of the C(2)-keto group. Enantioselectivities of the (R)- versus (S)-2-hydroxy-1-indanone varied from low to moderate in favor of the (R)-enantiomer. Springer Science+Business Media, LLC, 2007 1,2-indanedione nationallicence 2-hydroxy-1-indanone nationallicence heterogeneous hydrogenation nationallicence cinchonidine nationallicence Busygin Igor Laboratory of Organic Chemistry, Åbo Akademi University, Åbo, Finland aut Rosenholm Michael Laboratory of Organic Chemistry, Åbo Akademi University, Åbo, Finland aut Toukoniitty Esa Laboratory of Industrial Chemistry, Åbo Akademi University, Åbo, Finland aut Murzin Dmitry Laboratory of Industrial Chemistry, Åbo Akademi University, Åbo, Finland aut Leino Reko Laboratory of Organic Chemistry, Åbo Akademi University, Åbo, Finland aut Catalysis Letters Springer US; http://www.springer-ny.com 117/3-4(2007-09-01), 91-98 1011-372X 117:3-4<91 2007 117 10562 https://doi.org/10.1007/s10562-007-9123-8 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9123-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Busygin Igor Laboratory of Organic Chemistry, Åbo Akademi University, Åbo, Finland aut NATIONALLICENCE 700 1- Rosenholm Michael Laboratory of Organic Chemistry, Åbo Akademi University, Åbo, Finland aut NATIONALLICENCE 700 1- Toukoniitty Esa Laboratory of Industrial Chemistry, Åbo Akademi University, Åbo, Finland aut NATIONALLICENCE 700 1- Murzin Dmitry Laboratory of Industrial Chemistry, Åbo Akademi University, Åbo, Finland aut NATIONALLICENCE 700 1- Leino Reko Laboratory of Organic Chemistry, Åbo Akademi University, Åbo, Finland aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 117/3-4(2007-09-01), 91-98 1011-372X 117:3-4<91 2007 117 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer