caa a22 4500 463253922 CHVBK 20180405153348.0 cr unu---uuuuu 170326e20070801xx s 000 0 eng 10.1007/s10562-007-9151-4 doi (NATIONALLICENCE)springer-10.1007/s10562-007-9151-4 Controlling Reaction Pathways for Alcohol Dehydration and Dehydrogenation over FeSBA-15 Catalysts [Elektronische Daten] [Yejun Guan, Ying Li, Rutger van Santen, Emiel Hensen, Can Li] The iron location in FeSBA-15 strongly influences the selectivity to dehydrogenation and dehydration in ethanol conversion. At low iron loading, Fe is present as isolated $$\hbox{Fe}^{3+}$$ species in the amorphous silica phase. At higher loading additional aggregated forms of iron oxide exist. Isolated $$\hbox{Fe}^{3+}$$ species in the silica matrix imply Brønsted acidity resulting in selective formation of ethylene, whereas $$\hbox{FeO}_{\rm x}$$ clusters catalyze formation of ethylene and aldehyde. Springer Science+Business Media, LLC, 2007 SBA-15 nationallicence Iron nationallicence Ethanol nationallicence Dehydrogenation nationallicence Dehydration nationallicence Guan Yejun State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, Dalian, China aut Li Ying Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands aut van Santen Rutger Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands aut Hensen Emiel Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands aut Li Can State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, Dalian, China aut Catalysis Letters Springer US; http://www.springer-ny.com 117/1-2(2007-08-01), 18-24 1011-372X 117:1-2<18 2007 117 10562 https://doi.org/10.1007/s10562-007-9151-4 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10562-007-9151-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Guan Yejun State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, Dalian, China aut NATIONALLICENCE 700 1- Li Ying Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands aut NATIONALLICENCE 700 1- van Santen Rutger Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands aut NATIONALLICENCE 700 1- Hensen Emiel Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands aut NATIONALLICENCE 700 1- Li Can State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, Dalian, China aut NATIONALLICENCE 773 0- Catalysis Letters Springer US; http://www.springer-ny.com 117/1-2(2007-08-01), 18-24 1011-372X 117:1-2<18 2007 117 10562 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer