caa a22 4500 465729568 CHVBK 20180323111737.0 cr unu---uuuuu 170327e19901001xx s 000 0 eng 10.1007/BF02040323 doi (NATIONALLICENCE)springer-10.1007/BF02040323 Slanina Z. Max-Planck-Institut für Chemie (Otto-Hahn-Institut), Mainz, (FRG) aut Isotopic difference in the second virial coefficient of water: Another test of the MCY-B description of water dimer thermodynamics [Elektronische Daten] [Z. Slanina] Evaluation has been carried out of the component of the second virial coefficient of steam related to the formation of dimers. The necessary equilibrium constants of dimerization have been evaluated within the MCY-B water pair interaction potential. The calculated isotopic difference in the second virial coefficient reflects the qualitative features found by observation but, nevertheless, the calculation quite distinctly overestimates the value of this isotopic difference as compared with the observation. The nature of these differences and the relation to the state behaviour of water are discussed. Akadémiai Kiadó, 1990 Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 142/2(1990-10-01), 525-529 0236-5731 142:2<525 1990 142 10967 https://doi.org/10.1007/BF02040323 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02040323 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Slanina Z. Max-Planck-Institut für Chemie (Otto-Hahn-Institut), Mainz, (FRG) aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 142/2(1990-10-01), 525-529 0236-5731 142:2<525 1990 142 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer