caa a22 4500 465729606 CHVBK 20180323111737.0 cr unu---uuuuu 170327e19901001xx s 000 0 eng 10.1007/BF02040322 doi (NATIONALLICENCE)springer-10.1007/BF02040322 Gamma-radiolysis of solid zirconium nitrate and its binary mixtures with potassium halides [Elektronische Daten] [N. Joshi, A. Garg] Gamma-radiolytic decomposition of zirconium nitrate and its binary mixtures with potassium halides viz. KCl, KBr and KI has been studied at different compositions up to an absorbed dose of 550 kGy. Radiolytic decomposition has been found to decrease with the absorbed dose. It also varies with the concentration of zirconium nitrate in the binary mixtures. G(NO 2 − ) values are enhanced by the addition of halides but only at 75% composition. It is not affected so significantly by KI. A plot of G(NO 2 − ) vs. composition of the binary mixtures of the nitrates shows a somewhat parabolic curve with a minimum at 75% Zr(NO3)4+25% KX composition. A part of the energy absorbed by the system is being taken up by the halides depending upon their nature and concentration. Thermal decomposition shows slow decomposition, finally yielding an oxynitrate of indefinite composition. Akadémiai Kiadó, 1990 Joshi N. Department of Chemistry, Nagpur University, 440 010, Nagpur, (India) aut Garg A. Department of Chemistry, Nagpur University, 440 010, Nagpur, (India) aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 142/2(1990-10-01), 515-523 0236-5731 142:2<515 1990 142 10967 https://doi.org/10.1007/BF02040322 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02040322 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Joshi N. Department of Chemistry, Nagpur University, 440 010, Nagpur, (India) aut NATIONALLICENCE 700 1- Garg A. Department of Chemistry, Nagpur University, 440 010, Nagpur, (India) aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 142/2(1990-10-01), 515-523 0236-5731 142:2<515 1990 142 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer