caa a22 4500 465729649 CHVBK 20180323111738.0 cr unu---uuuuu 170327e19900901xx s 000 0 eng 10.1007/BF02199269 doi (NATIONALLICENCE)springer-10.1007/BF02199269 Spin crossover studies in cationic complexes of iron by using Mössbauer spectroscopy [Elektronische Daten] [S. Vadera, N. Kumar] The spin transitions in two new cationic complexes of iron, i. e., iron bipyridine formate, [Fe/bipy/3]/HCOO/2. 5/HCOOH/ and iron bipyridine tetrafluoro borate, [Fe/bipy/3]/BF4/2. 2H2O have been studied by using Mössbauer spectroscopy. From quadrupole splitting values, at different temperatures, it has been established that both the complexes show the coexistence of both the high spin state and the low spin state at 300 K while complete transformation to low spin state occurs at 77 K. Both compounds were prepared by electrochemical technique. Akadémiai Kiadó, 1990 Vadera S. Defence Laboratory, 342 001, Jodhpur, India aut Kumar N. Defence Laboratory, 342 001, Jodhpur, India aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 146/1(1990-09-01), 29-35 0236-5731 146:1<29 1990 146 10967 https://doi.org/10.1007/BF02199269 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02199269 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Vadera S. Defence Laboratory, 342 001, Jodhpur, India aut NATIONALLICENCE 700 1- Kumar N. Defence Laboratory, 342 001, Jodhpur, India aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 146/1(1990-09-01), 29-35 0236-5731 146:1<29 1990 146 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer