caa a22 4500 465729746 CHVBK 20180323111738.0 cr unu---uuuuu 170327e19901201xx s 000 0 eng 10.1007/BF02199262 doi (NATIONALLICENCE)springer-10.1007/BF02199262 Coulometric determination of uranium and iron or plutonium in a single aliquot using platinum working electrode [Elektronische Daten] [A. Joshi, U. Kasar] A controlled potential coulometric method developed earlier for the determination of uranium in the presence of iron or plutonium using platinum working electrode was extended for individual determination of uranium and iron or plutonium in single aliquot. After uranium determination, Fe(III) or Pu(IV) in the aliquot is reduced electrolytically to Fe(II) or Pu(III) and subsequently determined by electrolytic oxidation to Fe(III) or Pu(IV), respectively. Analysis of synthetic solutions indicated that the values for uranium, iron and plutonium obtained by this method are reproducible within±0.2% and are in good agreement with values obtained using conventional redox methods 1, 2. Akadémiai Kiadó, 1990 Joshi A. Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut Kasar U. Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 146/6(1990-12-01), 401-405 0236-5731 146:6<401 1990 146 10967 https://doi.org/10.1007/BF02199262 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02199262 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Joshi A. Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut NATIONALLICENCE 700 1- Kasar U. Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085, Bombay, India aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 146/6(1990-12-01), 401-405 0236-5731 146:6<401 1990 146 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer