caa a22 4500 465730663 CHVBK 20180323111740.0 cr unu---uuuuu 170327e19900501xx s 000 0 eng 10.1007/BF02037363 doi (NATIONALLICENCE)springer-10.1007/BF02037363 Chemical effects of nuclear transformations in mixed potassium hexahalogenometallates(IV), K2MXnY6−n [Elektronische Daten] II. Chemical effects of the35Cl(n, γ)36Cl,37Cl(n, γ)38Cl,79Br(n, γ)80mBr and81Br(n, γ)82Br nuclear processes in mixed potassium hexabromochlororhenates(IV), K2ReBrnCl6−n, and osmates, K2OsBrnCl6−n [H. Müller, I. Hagenlocher] Damage initiated by halogen recoil atoms in mixed hexabromochlorometallates has been evaluated with the help of the impact-induced multiple Ligand Abstraction (IMULA) model. The essential reactions within the scope of the model are (1) primary retention for recoil atoms with energies below some threshold of displacement energy, (2) halide-halide substitution reactions (billiard ball reactions), (3) reactions in which two or more halide ligands are displaced with subsequent reoccupation of the vacancies by adjacent halides and (4) formation of interstitials which form free halide during the dissolution of the irradiated substances. It was found that for all recoil atoms and both potassium hexabromochlorometallates the contributions of the different reaction channels are very similar: (1) 4-18% (2) 40-50%, (3) 25-30% and (4) 12-20% These results do not differ essentially from results so far obtained in mixed crystal systems. Akadémiai Kiadó, 1990 Müller H. Institut für Anorganische und Analytische Chemie, Abteilung Radiochemie, Universität Freiburg, Albertstr. 21, D-7800, Freiburg i. Br., FRG aut Hagenlocher I. Institut für Anorganische und Analytische Chemie, Abteilung Radiochemie, Universität Freiburg, Albertstr. 21, D-7800, Freiburg i. Br., FRG aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 140/1(1990-05-01), 37-56 0236-5731 140:1<37 1990 140 10967 https://doi.org/10.1007/BF02037363 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02037363 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Müller H. Institut für Anorganische und Analytische Chemie, Abteilung Radiochemie, Universität Freiburg, Albertstr. 21, D-7800, Freiburg i. Br., FRG aut NATIONALLICENCE 700 1- Hagenlocher I. Institut für Anorganische und Analytische Chemie, Abteilung Radiochemie, Universität Freiburg, Albertstr. 21, D-7800, Freiburg i. Br., FRG aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 140/1(1990-05-01), 37-56 0236-5731 140:1<37 1990 140 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer