caa a22 4500 465731325 CHVBK 20180323111742.0 cr unu---uuuuu 170327e19900701xx s 000 0 eng 10.1007/BF02163416 doi (NATIONALLICENCE)springer-10.1007/BF02163416 ‘Effective hot reaction zone', caging energy and normalized appearance energy in ruthenium complexes [Elektronische Daten] [H. Matsue, I. Kaneko, T. Sekine, K. Yoshihara] In contrast to the single molecule cage of Ru/acac/3 a cage involving wall molecules of RuCp2 is formed in recoil reaction of radioruthenium atoms. Enhancement of the parent yield in RuCp2 is ascribed to the larger size of the cage /effective hot reaction zone/ compared to the case of Ru/acac/3. A normalized appearance energy technique has been applied to estimate energy /AE adj x / necessary for caging the recoil atom in RuCp2. AE adj x is about twice as large as caging energy CE. The relation of AE adj x to CE in RuCp2 is nearly the same as that of AEx to bonding energy BE in Ru/acac/3. Akadémiai Kiadó, 1990 Matsue H. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut Kaneko I. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut Sekine T. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut Yoshihara K. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 145/4(1990-07-01), 271-280 0236-5731 145:4<271 1990 145 10967 https://doi.org/10.1007/BF02163416 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02163416 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Matsue H. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut NATIONALLICENCE 700 1- Kaneko I. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut NATIONALLICENCE 700 1- Sekine T. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut NATIONALLICENCE 700 1- Yoshihara K. Department of Chemistry, Faculty of Science, Tohoku University, 980, Sendai, Japan aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 145/4(1990-07-01), 271-280 0236-5731 145:4<271 1990 145 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer