caa a22 4500 465731473 CHVBK 20180323111742.0 cr unu---uuuuu 170327e19900501xx s 000 0 eng 10.1007/BF02172361 doi (NATIONALLICENCE)springer-10.1007/BF02172361 Thermal decomposition of γ-irradiated cadmium bromate [Elektronische Daten] [S. Nair, P. Jacob] The thermal decomposition of γ-irradiated cadmium bromate was studied by dynamic thermogravimetry. The reaction order, activation energy, frequency factor and entropy of activation were computed using the Coats-Redfern method and were compared with those of the unirradiated salt. Irradiation enhances the decomposition and the effect increases with irradiation dose. The activation energy decreases on irradiation. The mechanism for the decomposition of unirradiated and irradiated cadmium bromate follows the Avrami model equation, 1-/1-α/1/3=kt, and the ratecontrolling process is a phase-boundary reaction assuming spherical symmetry. Akadémiai Kiadó, 1990 Nair S. Department of Chemistry, University of Calicut, 673 635, Kerala, India aut Jacob P. Department of Chemistry, University of Calicut, 673 635, Kerala, India aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 145/2(1990-05-01), 103-111 0236-5731 145:2<103 1990 145 10967 https://doi.org/10.1007/BF02172361 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02172361 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Nair S. Department of Chemistry, University of Calicut, 673 635, Kerala, India aut NATIONALLICENCE 700 1- Jacob P. Department of Chemistry, University of Calicut, 673 635, Kerala, India aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 145/2(1990-05-01), 103-111 0236-5731 145:2<103 1990 145 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer