caa a22 4500 465732445 CHVBK 20180323111745.0 cr unu---uuuuu 170327e19901101xx s 000 0 eng 10.1007/BF02117550 doi (NATIONALLICENCE)springer-10.1007/BF02117550 Uranyl compounds and complexes: Electronic structure, chemical bonding and spectral properties [Elektronische Daten] [M. Ryzhkov, V. Gubanov] The electronic structure of solid compounds γ-UO3, Cs2UO2CL4, UO2F4 and complexes UO 2 2+ and UO2(NO3)2 · 2H2O has been studied by the cluster discrete variational DV Xα method in Dirac-Slater and Hartree-Fock-Slater approximation. The analysis of relativistic effects in the electronic structure of uranyl compounds was based on the comparison of non-relativistic and relativistic DV results. The interpretation of X-ray photoelectron spectra of γ-UO3 and Cs2UO2Cl4 basing on the MO model is given. The various electronic states contributions to the chemical bonding in uranyl compounds are investigated. Akadémiai Kiadó, 1990 Ryzhkov M. Institute of Chemistry, Ural Branch of the USSR, Academy of Sciences, 620219, Sverdlovsk, (USSR) aut Gubanov V. Institute of Chemistry, Ural Branch of the USSR, Academy of Sciences, 620219, Sverdlovsk, (USSR) aut Journal of Radioanalytical and Nuclear Chemistry Articles Springer Netherlands 143/1(1990-11-01), 85-92 0236-5731 143:1<85 1990 143 10967 https://doi.org/10.1007/BF02117550 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02117550 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ryzhkov M. Institute of Chemistry, Ural Branch of the USSR, Academy of Sciences, 620219, Sverdlovsk, (USSR) aut NATIONALLICENCE 700 1- Gubanov V. Institute of Chemistry, Ural Branch of the USSR, Academy of Sciences, 620219, Sverdlovsk, (USSR) aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Articles Springer Netherlands 143/1(1990-11-01), 85-92 0236-5731 143:1<85 1990 143 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer