caa a22 4500 465732747 CHVBK 20180323111746.0 cr unu---uuuuu 170327e19901201xx s 000 0 eng 10.1007/BF02039613 doi (NATIONALLICENCE)springer-10.1007/BF02039613 Vladimirova M. All-Union Scientific Research Institute of Inorganic Materials, Moscow, USSR aut Radiation chemistry of actinides [Elektronische Daten] [M. Vladimirova] The paper presents data on the development of a mathematical model describing the radiation-chemical behaviour of plutonium in 3-6 mol/l HNO3 with uranium present and absent. Using experimental data on the kinetics of Pu(VI) reduction and Pu(IV) oxidation, and comparing them with the calculated values, we succeeded in finding the previously unknown rate constants of many reactions between plutonium ions and HNO3 radiolysis products, between plutonium ions and between plutonium ions and uranium ions. The mechanism of the radiation-chemical processes has been established. Akadémiai Kiadó, 1990 Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 143/2(1990-12-01), 445-454 0236-5731 143:2<445 1990 143 10967 https://doi.org/10.1007/BF02039613 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02039613 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Vladimirova M. All-Union Scientific Research Institute of Inorganic Materials, Moscow, USSR aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 143/2(1990-12-01), 445-454 0236-5731 143:2<445 1990 143 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer