caa a22 4500 465733212 CHVBK 20180323111747.0 cr unu---uuuuu 170327e19900301xx s 000 0 eng 10.1007/BF02218142 doi (NATIONALLICENCE)springer-10.1007/BF02218142 Effect of transition metal chloride additives on the radiolysis of aqueous sodium nitrate [Elektronische Daten] [C. Kalkar, M. Bhujbal, Rajashree Barve] Radiolysis of aqueous sodium nitrate solution was studied as a function of concentration in the range 10−4M to 1M NaNO3. The radiolytic yield of nitrite was found to be linear with dose and concentration. The effect of transition metal chloride additives on the radiolysis of 0.01M NaNO3 resulted in higher and lower yields of nitrite in the presence of cobalt and nickel chlorides, respectively, than that obtained in the pure nitrate system. The reduction of nitrate to nitrite is totally quenched even at very low concentration of copper chloride in the binary mixture. The results are explained on the basis of oxidizing and reducing properties of transition metal ions. Akadémiai Kiadó, 1990 Kalkar C. Department of Chemistry, University of Poona, 411 007, Pune, India aut Bhujbal M. Department of Chemistry, University of Poona, 411 007, Pune, India aut Barve Rajashree Department of Chemistry, University of Poona, 411 007, Pune, India aut Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 144/5(1990-03-01), 351-358 0236-5731 144:5<351 1990 144 10967 https://doi.org/10.1007/BF02218142 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02218142 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kalkar C. Department of Chemistry, University of Poona, 411 007, Pune, India aut NATIONALLICENCE 700 1- Bhujbal M. Department of Chemistry, University of Poona, 411 007, Pune, India aut NATIONALLICENCE 700 1- Barve Rajashree Department of Chemistry, University of Poona, 411 007, Pune, India aut NATIONALLICENCE 773 0- Journal of Radioanalytical and Nuclear Chemistry Kluwer Academic Publishers 144/5(1990-03-01), 351-358 0236-5731 144:5<351 1990 144 10967 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer