caa a22 4500 465743307 CHVBK 20180323111813.0 cr unu---uuuuu 170327e19901001xx s 000 0 eng 10.1007/BF02707178 doi (NATIONALLICENCE)springer-10.1007/BF02707178 Chemical equilibria in methanol synthesis from methyl formate [Elektronische Daten] [Kwang Kim, Jae Kim, Minsek Cheong, Jae Lee, Young Kim] The chemicalequilibria of the gas-phase methanol production from methyl formate were studied by analyzing the hydrugenolysis reaction (HCOOCH3+ 2H2 -2CH3OH) and decarbonylation reaction (HCOOCH3 CH3OH + CO) occurring concurrently.The equilibrium constant, which includes the effects of nonideality, was estimated fur each reaction using equations of state. Equilibrium composition for each constituent in this reaction system was evaluated in relation to temperature, pressure, and initial concentration ratio (H2/HCOOCH3), and the effect of CO feed on equilibrium conversion of methyl formate was also discussed. General guidelines lo improve the selectivity of hydrogenulysis reaction were proposed. Korean Institute of Chemical Engineering, 1990 Kim Kwang Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut Kim Jae Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut Cheong Minsek Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut Lee Jae Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut Kim Young Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut Korean Journal of Chemical Engineering Springer-Verlag 7/4(1990-10-01), 259-268 0256-1115 7:4<259 1990 7 11814 https://doi.org/10.1007/BF02707178 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02707178 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kim Kwang Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut NATIONALLICENCE 700 1- Kim Jae Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut NATIONALLICENCE 700 1- Cheong Minsek Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut NATIONALLICENCE 700 1- Lee Jae Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut NATIONALLICENCE 700 1- Kim Young Chemical Engineering Division, Research Institute of Industrial Science and Technology (RIST), P.O. Box 135, 790-600, Pohang, Korea aut NATIONALLICENCE 773 0- Korean Journal of Chemical Engineering Springer-Verlag 7/4(1990-10-01), 259-268 0256-1115 7:4<259 1990 7 11814 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer