caa a22 4500 465747728 CHVBK 20180323111825.0 cr unu---uuuuu 170327e19900101xx s 000 0 eng 10.1007/BF00322860 doi (NATIONALLICENCE)springer-10.1007/BF00322860 Laser ablation and furnace techniques for sampling and detection in atomic emission spectrometry [Elektronische Daten] [K. Dittrich, I. Mohamad, H. Nguyen, K. Niebergall, M. Pfeifer, R. Wennrich] Summary: The potential of furnace techniques and of laser evaporation for the analysis of dry solution residues and of solids by different atomic emission procedures is described. The new one-step FANES technique (furnace atomic nonthermal emission spectrometry) is compared with the two-step procedure ETV-ICP-AES (electrothermal vaporisation—inductively coupled plasma—atomic emission spectrometry). In case of dry solution residues the sensitivity of the FANES is higher (1-2 orders of magnitude) as a result of better discharge conditions (low background) and direct sample introduction, particularly for volatile and moderately volatile substances. For refractory elements the higher gas temperature of the ICP plasma causes better atomisation, which can lead to higher sensitivity of the ETV-ICP-AES. A new Laser-FANES hybride technique is introduced for microanalysis in solid samples and compared with Laser-ICP-AES. The Laser-FANES is shown to combine the advantages of Laser-ETA-AAS (high sensitivity) and of Laser-ICP-AES (multielemental determinations), particularly for volatile and moderately volatile elements. Springer-Verlag, 1990 Dittrich K. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut Mohamad I. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut Nguyen H. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut Niebergall K. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut Pfeifer M. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut Wennrich R. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut Fresenius' Journal of Analytical Chemistry Springer-Verlag 337/5(1990-01-01), 546-550 0937-0633 337:5<546 1990 337 216 https://doi.org/10.1007/BF00322860 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00322860 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Dittrich K. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 700 1- Mohamad I. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 700 1- Nguyen H. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 700 1- Niebergall K. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 700 1- Pfeifer M. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 700 1- Wennrich R. Karl-Marx-Universität Leipzig, Sektion Chemie, Talstrasse 35, DDR-7010, Leipzig, German Democratic Republic aut NATIONALLICENCE 773 0- Fresenius' Journal of Analytical Chemistry Springer-Verlag 337/5(1990-01-01), 546-550 0937-0633 337:5<546 1990 337 216 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer