caa a22 4500 465748414 CHVBK 20180323111827.0 cr unu---uuuuu 170327e19900101xx s 000 0 eng 10.1007/BF00323195 doi (NATIONALLICENCE)springer-10.1007/BF00323195 Kinetic fluorimetric determination of carbamazepine in serum by the stopped-flow technique [Elektronische Daten] [L. de la Peña, A. Gomez-Hens, D. Pérez-Bendito] Summary: A simple, fast method for the determination of carbamazepine in serum is reported for the first time. It is based on the fluorescent reaction of this drug with cerium(IV) in an acid medium. A stopped-flow mixing module coupled to a conventional spectrofluorimeter is used for this purpose. The linear range of the proposed method is 0.04-140 μg ml−1 of carbamazepine and the detection limit is 0.01 μg ml−1. The within- and between-assay precision data and selectivity results show the method to be adequate for the determination of carbamazepine in serum by including a preliminary extraction step with dichloromethane. Analytical recoveries from different serum samples are reported. Springer-Verlag, 1990 de la Peña L. Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, E-14004, Córdoba, Spain aut Gomez-Hens A. Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, E-14004, Córdoba, Spain aut Pérez-Bendito D. Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, E-14004, Córdoba, Spain aut Fresenius' Journal of Analytical Chemistry Springer-Verlag 338/7(1990-01-01), 821-823 0937-0633 338:7<821 1990 338 216 https://doi.org/10.1007/BF00323195 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00323195 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- de la Peña L. Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, E-14004, Córdoba, Spain aut NATIONALLICENCE 700 1- Gomez-Hens A. Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, E-14004, Córdoba, Spain aut NATIONALLICENCE 700 1- Pérez-Bendito D. Department of Analytical Chemistry, Faculty of Sciences, University of Córdoba, E-14004, Córdoba, Spain aut NATIONALLICENCE 773 0- Fresenius' Journal of Analytical Chemistry Springer-Verlag 338/7(1990-01-01), 821-823 0937-0633 338:7<821 1990 338 216 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer