caa a22 4500 465755038 CHVBK 20180323111844.0 cr unu---uuuuu 170327e19900601xx s 000 0 eng 10.1007/BF01166428 doi (NATIONALLICENCE)springer-10.1007/BF01166428 Bhalekar Anil Chemistry Department, Nagpur University, The Campus, 440010, Nagpur, India aut On the generalized phenomenological irreversible thermodynamic theory (GPITT) [Elektronische Daten] [Anil Bhalekar] An outline of a new mathematical theory is presented, namely, the generalized phenomenological irreversible thermodynamic theory (GPITT) evolved by the author. This theory involves the identification of a new mathematical quantity designated as the thermodynamic heat (which is different from Born's mechanically definable one) and the adoption of a Universal Inaccessibility Principle (UIP) which yields the simplest extended Gibbs relation (EGR). The second law inequalities are thereby generalized and provide appropriate constraints on open systems. The potentiality of GPITT has been discussed with reference to Boltzmann'sH-function and the thermodynamic entropy concept, and also in regard to the development of the abstract thermodynamic description, in particular with reference to the extended Gibbsian space (EGS) provided by the EGR as against the currently used Gibbsian space (GS). J.C. Baltzer AG, Scientific Publishing Company, 1990 Journal of Mathematical Chemistry Kluwer Academic Publishers 5/2(1990-06-01), 187-196 0259-9791 5:2<187 1990 5 10910 https://doi.org/10.1007/BF01166428 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF01166428 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Bhalekar Anil Chemistry Department, Nagpur University, The Campus, 440010, Nagpur, India aut NATIONALLICENCE 773 0- Journal of Mathematical Chemistry Kluwer Academic Publishers 5/2(1990-06-01), 187-196 0259-9791 5:2<187 1990 5 10910 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer